demeanor
The definition for demeanor is "Behavior towards others." Used in a sentence: Carlos was well liked because of his charming demeanor.
discern
The definition for discern is "To recognize as separate as distinct." Used in a sentence: The pastry connoisseur was able to discern Swiss from Belgian chocolate.
negate
The definition for negate is "To make invalid." Used in a sentence: Paula negated Tiffany's argument by proving that her main premise was false.
opportune
The definition for opportune is "Suitable or convenient." Used in a sentence: Quan stepped onto the platform at the most opportune time, just as the train pulled in.
regale
The definition for regale is "To amuse." Used in a sentence: My clever brother Jeffrey regaled the dinner guests with tales of his adventures.